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Disposal And Recycling
Since organotin stabilizers are firmly bound into the PVC matrix and
do not migrate, a general description of recycling and disposal of PVC
is sufficient.
Landfilling
Up till now, no decomposition of rigid PVC in landfills could be detected.
Since stabilizers do not migrate from the bulk plastic, organotin compounds
from PVC elute to a negligible extent into landfill leachates. In order
to validate these results, the PVC-industry has initiated a study with
academic institutions about the long-term effect of PVC and its additives
in landfills. ORTEPA is taking part in this study.
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Incineration
Domestic waste (e.g., in Germany) contains 7 to 8 percent of plastics,
with a mere 0.7 percent of PVC [40]. Only in a small part of this PVC
organotin stabilizers are used. During incineration all tin compounds
are transformed to tin dioxide, which is found in the ashes and in the
dusts collected at the flue gas purification equipment. A significant
amount of this tin, however, originates from products other than PVC.
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Recycling
Being a thermoplastic, PVC can be remelted and reprocessed several times.
PVC stabilized with organotin compounds can be reprocessed together with
other recyclates. Organotin mercaptides together with lead may cause some
discoloration, which, however, is irrelevant for most applications or
can be avoided by using sulfur free tin stabilizers. After longer periods
of weathering, restabilization before reprocessing may be necessary.
Scrap from production and used PVC articles are being returned increasingly
into the production stream. Used food packaging (films, bottles, and beakers�.)
will not be used again for food contact articles, mainly due to regulatory
reasons. However, it is used for other applications. PVC can be reprocessed
into shoe soles, waste water pipes, floor tiles, etc. Mixtures of PVC
and other plastics are used to manufacture e.g., walls for noise protection,
garden furniture, fences, gutters, and other technical applications.
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